NEET 2024 Chemistry Question 95 Solution
Question
A compound X contains 32% of A, 20% of B and remaining percentage of C. Then, the empirical formula of X is: (Given atomic masses of A = 64; B = 40; C = 32 u)
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A compound X contains 32% of A, 20% of B and remaining percentage of C. Then, the empirical formula of X is: (Given atomic masses of A = 64; B = 40; C = 32 u)
% C = 100 - (32 + 20) = 48%! Moles: A = 32/64 = 0.5; B = 20/40 = 0.5; C = 48/32 = 1.5! Divide by 0.5 -> 1 : 1 : 3 -> ABC3!
The sum of percentages of all constituent elements in compound X must equal 100%:
Dividing the mass percentage of each element by its respective atomic mass: - Element A: n_A = 32 g / 64 g/mol = 0.50 mol - Element B: n_B = 20 g / 40 g/mol = 0.50 mol - Element C: n_C = 48 g / 32 g/mol = 1.50 mol
Dividing all mole numbers by the smallest mole value (0.50):
The atomic ratio 1 : 1 : 3 yields the empirical formula ABC3:
Diagnose every choice: Know exactly why the right option works and why distractors fail.
Incorrect atomic ratio.
Overestimates oxygen/C count.
Inverts stoichiometry of A and C.
Exact whole-number molar ratio: 0.5 : 0.5 : 1.5 = 1 : 1 : 3.
The question gives percentages for A and B only, leaving C as "remaining percentage". Always compute %C = 100 - (32 + 20) = 48% first.
"Empirical formula represents the simplest whole number ratio of atoms of various elements present in one molecule of the compound."
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