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Q.51 Chemistry · Section A ⭐ 360° Option Elimination Active
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NEET 2024 Chemistry Question 51 Solution

Topic: Thermodynamics · Official NTA Booklet Code T1
NEET 2024 Chemistry Question 51: Classification of Thermodynamic Processes

Question

Match List I (Process) with List II (Conditions). List I: A. Isothermal process; B. Isochoric process; C. Isobaric process; D. Adiabatic process. List II: I. No heat exchange; II. Carried out at constant temperature; III. Carried out at constant volume; IV. Carried out at constant pressure. Choose the correct answer from the options given below:

✓
Verified Against NTA Final Answer Key
Option (2) : A-II, B-III, C-IV, D-I
📚 Thermodynamics Easy
📋 Given Parameters & Problem Setup
Process A Isothermal process
Process B Isochoric process
Process C Isobaric process
Process D Adiabatic process
⚡

The 30-Second Exam Hall Shortcut: ⚡ Thermodynamic Terminology Direct Match

⏱️ Save ~40 seconds

Iso-thermal (constant T -> II), Iso-choric (constant V -> III), Iso-baric (constant P -> IV), Adiabatic (q = 0, no heat exchange -> I)!

1 "Thermal" refers to temperature -> Isothermal = constant temperature (A-II).
2 "Choric" refers to volume -> Isochoric = constant volume (B-III).
3 "Baric" refers to pressure -> Isobaric = constant pressure (C-IV).
4 "Adiabatic" refers to no heat exchange between system and surroundings: q = 0 (D-I).
5 Matching sequence: A-II, B-III, C-IV, D-I -> Option (2) in 5 seconds!
🛡️
Why You Can 100% Trust This Shortcut: NCERT Chemistry · Thermodynamics (Basic thermodynamic definitions and path classifications).
📐

Step-by-Step Rigorous Workflow & Mathematical Proof

Step 1

Definition of Isothermal Process

An isothermal process is one in which the temperature of the system remains constant throughout the entire thermodynamic change:

ΔT=0  ⟹  T=constant\Delta T = 0 \implies T = \text{constant}
Step 2

Definition of Isochoric Process

An isochoric process is one in which the total volume of the system remains strictly constant. As a result, no mechanical boundary work is performed by the system:

ΔV=0  ⟹  V=constant,W=∫P dV=0\Delta V = 0 \implies V = \text{constant}, \quad W = \int P\, dV = 0
Step 3

Definition of Isobaric Process

An isobaric process is carried out at constant pressure. The heat exchanged at constant pressure equals the enthalpy change:

ΔP=0  ⟹  P=constant,qp=ΔH\Delta P = 0 \implies P = \text{constant}, \quad q_p = \Delta H
Step 4

Definition of Adiabatic Process

An adiabatic process is thermally insulated such that no heat flows into or out of the system. According to the First Law of Thermodynamics, all work done is at the expense of internal energy:

q=0  ⟹  ΔU=wadq = 0 \implies \Delta U = w_{ad}
⭐

360° Option Elimination Engine Key Feature

Diagnose every choice: Know exactly why the right option works and why distractors fail.

4-Option Deep Scan
1 (1)
✗ Incorrect
Verdict & Scientific Reason:

Mismatches isothermal with adiabatic.

⚠️
Student Fallacy (Why candidates pick this trap): Associating isothermal with zero heat.
2 (2)
✓ 100% Correct
Verdict & Scientific Reason:

Exact match with canonical physical definitions.

💡
Why this is airtight: None.
3 (3)
✗ Incorrect
Verdict & Scientific Reason:

Inverts isobaric and isothermal.

⚠️
Student Fallacy (Why candidates pick this trap): Confusing baric (pressure) with thermal (temperature).
4 (4)
✗ Incorrect
Verdict & Scientific Reason:

Mismatches both isothermal and isochoric.

⚠️
Student Fallacy (Why candidates pick this trap): Random association of prefixes.
⚠️

NTA Trap Alert: Confusing Isothermal (ΔT=0) with Adiabatic (q=0)

Students frequently confuse isothermal (constant temperature with heat exchange allowed) with adiabatic (strictly zero heat exchange).

🛡️ How to avoid the -1 mark: Remember: In an ideal gas isothermal expansion, heat enters the system to maintain constant temperature: q = -w > 0.
📖

Core NEET Syllabus Standard

Chemistry Core Physical Chemistry · Thermodynamics Standard Benchmark
Core Scientific Principle Tested:

"Thermodynamic processes are defined by the thermodynamic variable held invariant: Isothermal (T), Isochoric (V), Isobaric (P), and Adiabatic (q = 0)."

Syllabus Focus: Types of Processes: Isothermal, Adiabatic, Isobaric, and Isochoric
✓ Core NEET UG Syllabus Anchor Syllabus & Academic Standards ↗
Thermal is Temp, Choric is Container (Volume), Baric is Barometer (Pressure), Adiabatic has Zero Heat!

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