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Q.125 Botany ⭐ 360° Option Elimination Active
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NEET 2023 Botany Question 125 Solution

Topic: Mineral Nutrition · Official NTA Booklet Code G5
NEET 2023 Botany Question 125: Role of Manganese in Photolysis of Water

Question

Which micronutrient is required for splitting of water molecule during photosynthesis?

  1. (1)copper
  2. (2)manganese
  3. (3)molybdenum
  4. (4)magnesium
✓
Verified Against NTA Final Answer Key
Option (2) : manganese
📚 Mineral Nutrition Easy
📋 Given Parameters & Problem Setup
Biochemical Event Splitting of water (Photolysis) in PS II
Nutrient Category Micronutrient (Trace element)
⚡

The 30-Second Exam Hall Shortcut: ⚡ Photolysis of Water = Manganese (MnMn) & Chlorine (ClCl)

⏱️ Save ~20 seconds

The oxygen-evolving complex (OEC) of PS II contains a catalytic cluster of 4 manganese atoms (Mn4CaO5Mn_4CaO_5). NCERT explicitly states: "The best defined function of manganese is in the splitting of water to liberate oxygen during photosynthesis!"

1 Copper: Component of plastocyanin and cytochrome oxidase, redox reactions.
2 Molybdenum: Component of nitrogenase and nitrate reductase.
3 Magnesium: Central ring atom in chlorophyll, activator for RuBisCO/PEPCase (Macronutrient).
4 Manganese: Photolysis of water to liberate oxygen (Micronutrient).
5 Match Option (2) manganese.
🛡️
Why You Can 100% Trust This Shortcut: Canonical NCERT Mineral Nutrition micronutrient physiological roles.
📐

Step-by-Step Rigorous Workflow & Mathematical Proof

Step 1

Mechanism of Water Splitting in Photosystem II

Photolysis occurs on the inner (lumenal) face of the thylakoid membrane associated with PS II, requiring manganese (Mn2+Mn^{2+}), calcium (Ca2+Ca^{2+}), and chloride (Cl−Cl^-) ions:

2H2O→[Mn4CaO5 cluster]4H++4e−+O2↑2H_2O \xrightarrow{[Mn_4CaO_5\text{ cluster}]} 4H^+ + 4e^- + O_2\uparrow
Step 2

Verbatim NCERT Association

Under Manganese (MnMn), NCERT explicitly declares: "The best defined function of manganese is in the splitting of water to liberate oxygen during photosynthesis."

Step 3

Nutrient Classification Clarification

The question specifically stipulates "micronutrient". While magnesium (MgMg) is essential for photosynthesis as the central porphyrin ring coordinator of chlorophyll, magnesium is a macronutrient, whereas manganese is a micronutrient.

⭐

360° Option Elimination Engine Key Feature

Diagnose every choice: Know exactly why the right option works and why distractors fail.

4-Option Deep Scan
1 1
✗ Incorrect
Verdict & Scientific Reason:

Copper participates in electron transfer as a component of plastocyanin, but does not split water.

⚠️
Student Fallacy (Why candidates pick this trap): Confusing plastocyanin copper with the water-splitting complex.
2 2
✓ 100% Correct
Verdict & Scientific Reason:

Matches NCERT verbatim: manganese is the key catalytic micronutrient required for the photolysis of water.

💡
Why this is airtight: None; textbook verbatim.
3 3
✗ Incorrect
Verdict & Scientific Reason:

Molybdenum is an essential cofactor for nitrogenase and nitrate reductase in nitrogen metabolism.

⚠️
Student Fallacy (Why candidates pick this trap): Confusing nitrogen fixation enzymes with oxygen-evolving complexes.
4 4
✗ Incorrect
Verdict & Scientific Reason:

Magnesium is a macronutrient coordinated in the central ring of chlorophyll and an activator of RuBisCO; it does not split water.

⚠️
Student Fallacy (Why candidates pick this trap): Overlooking that magnesium is a macronutrient and does not catalyze photolysis.
⚠️

NTA Trap Alert: Manganese vs. Magnesium Trap

Students frequently mix up Manganese (MnMn, micronutrient for photolysis) with Magnesium (MgMg, macronutrient in chlorophyll core).

🛡️ How to avoid the -1 mark: Remember: Mg = in the middle of Green chlorophyll (Macro). Mn = split water to Make oxygen (Micro).
📖

Core NEET Syllabus Standard

NCERT Biology · Mineral Nutrition Standard Benchmark
Core Scientific Principle Tested:

"The best defined function of manganese is in the splitting of water to liberate oxygen during photosynthesis."

Syllabus Focus: Essential Mineral Elements (Manganese)
✓ Core NEET UG Syllabus Anchor Syllabus & Academic Standards ↗

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