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Q.26 Physics ⭐ 360° Option Elimination Active
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NEET 2021 Physics Question 26 Solution

Topic: Kinetic Theory · Official NTA Booklet Code M1
NEET 2021 Physics Question 26: Kinetic Theory Formulae: RMS Speed, Pressure, Molecular Kinetic Energy, and Internal Energy

Question

Match Column - I and Column - II and choose the correct match from the given choices. Column - I Column - II (A) Root mean square (P) 1 nm v speed of gas molecules (B) Pressure exerted (Q) 3 RT by ideal gas (C) Average kinetic energy (R) 5 RT of a molecule (D) Total internal energy (S) 3 k T of 1 mole of a diatomic gas

  1. (1)(A) - (R), (B) - (P), (C) - (S), (D) - (Q)
  2. (2)(A) - (Q), (B) - (R), (C) - (S), (D) - (P)
  3. (3)(A) - (Q), (B) - (P), (C) - (S), (D) - (R)
  4. (4)(A) - (R), (B) - (Q), (C) - (P), (D) - (S)
✓
Verified Against NTA Final Answer Key
Option (3) : (A) - (Q), (B) - (P), (C) - (S), (D) - (R)
📚 Kinetic Theory Easy
📋 Given Parameters & Problem Setup
Column I (A) Root mean square speed, (B) Pressure exerted by ideal gas, (C) Average KE of a molecule, (D) Total internal energy of 1 mole of diatomic gas
Column II (P) 1/3 n m v_bar^2, (Q) \sqrt{3RT / M}, (R) 5/2 RT, (S) 3/2 k_B T
⚡

The 30-Second Exam Hall Shortcut: ⚡ Kinetic Theory Master Matcher

⏱️ Save ~25 seconds

Match standard NCERT kinetic theory relations: RMS speed vrms=3RTMv_{\text{rms}} = \sqrt{\frac{3RT}{M}} (Q); Pressure P=13nmvˉ2P = \frac{1}{3} n m \bar{v}^2 (P); Average KE of one molecule =32kBT= \frac{3}{2} k_B T (S); Internal energy of 1 mole of diatomic gas (f=5f=5) =52RT= \frac{5}{2} RT (R)! Match Option (3)!

1 RMS speed of gas molecules: vrms=3RTM  ⟹  (A)−(Q)v_{\text{rms}} = \sqrt{\frac{3RT}{M}} \implies (A)-(Q).
2 Pressure of ideal gas: P=13nmvˉ2  ⟹  (B)−(P)P = \frac{1}{3} n m \bar{v}^2 \implies (B)-(P).
3 Translational KE per single molecule: Eˉ=32kBT  ⟹  (C)−(S)\bar{E} = \frac{3}{2} k_B T \implies (C)-(S).
4 Total internal energy for 1 mole of diatomic gas (f=5f = 5 degrees of freedom): U=f2RT=52RT  ⟹  (D)−(R)U = \frac{f}{2} RT = \frac{5}{2} RT \implies (D)-(R).
5 Match combination: (A)-(Q), (B)-(P), (C)-(S), (D)-(R) -> Option (3).
🛡️
Why You Can 100% Trust This Shortcut: Canonical Maxwell-Boltzmann kinetic theory of ideal gases and equipartition of energy theorem.
📐

Step-by-Step Rigorous Workflow & Mathematical Proof

Step 1

Formula for RMS Speed of Gas Molecules (A)

From kinetic theory of gases, the root mean square speed is directly proportional to the square root of absolute temperature:

vrms=3RTM  ⟹  (A)−(Q)v_{\text{rms}} = \sqrt{\frac{3RT}{M}} \implies \mathbf{(A)-(Q)}
Step 2

Formula for Pressure Exerted by an Ideal Gas (B)

Derived by considering rate of change of momentum of gas molecules bombarding container walls, where nn is number density, mm is molecular mass, and vˉ2\bar{v}^2 is mean square speed:

P=13nmvˉ2  ⟹  (B)−(P)P = \frac{1}{3} n m \bar{v}^2 \implies \mathbf{(B)-(P)}
Step 3

Formula for Average Kinetic Energy of a Molecule (C)

By the equipartition of energy theorem, each translational degree of freedom contributes 12kBT\frac{1}{2} k_B T. For 3 translational degrees of freedom of a single molecule:

Eavg=3×(12kBT)=32kBT  ⟹  (C)−(S)E_{\text{avg}} = 3 \times \left(\frac{1}{2} k_B T\right) = \frac{3}{2} k_B T \implies \mathbf{(C)-(S)}
Step 4

Formula for Total Internal Energy of 1 Mole of Diatomic Gas (D)

A rigid diatomic gas has 5 degrees of freedom (3 translational + 2 rotational). For 1 mole (n=1n = 1), the internal energy is:

U=f2nRT=52(1)RT=52RT  ⟹  (D)−(R)U = \frac{f}{2} n R T = \frac{5}{2} (1) R T = \frac{5}{2} R T \implies \mathbf{(D)-(R)}
⭐

360° Option Elimination Engine Key Feature

Diagnose every choice: Know exactly why the right option works and why distractors fail.

4-Option Deep Scan
1 1
✗ Incorrect
Verdict & Scientific Reason:

Mismatches RMS speed with internal energy 52RT\frac{5}{2}RT.

⚠️
Student Fallacy (Why candidates pick this trap): Swapping (A) and (D).
2 2
✗ Incorrect
Verdict & Scientific Reason:

Mismatches pressure with internal energy.

⚠️
Student Fallacy (Why candidates pick this trap): Swapping (B) and (D).
3 3
✓ 100% Correct
Verdict & Scientific Reason:

Exact 1-to-1 match with all four textbook kinetic theory relations.

💡
Why this is airtight: None; textbook verbatim match.
4 4
✗ Incorrect
Verdict & Scientific Reason:

Scrambles multiple associations.

⚠️
Student Fallacy (Why candidates pick this trap): Random matching.
⚠️

NTA Trap Alert: Molar Energy (R) vs. Molecular Energy (k_B) Trap

Students frequently mix up molecular kinetic energy (which uses Boltzmann's constant kBk_B) with molar internal energy (which uses the universal gas constant RR).

🛡️ How to avoid the -1 mark: Molecule = uses kBk_B (Option S). Mole of gas = uses RR (Option R).
📖

Core NEET Syllabus Standard

NCERT Physics · Kinetic Theory Standard Benchmark
Core Scientific Principle Tested:

"Pressure is P=13nmvˉ2P = \frac{1}{3}nm\bar{v}^2; RMS speed is 3RT/M\sqrt{3RT/M}; average molecular KE is 32kBT\frac{3}{2}k_BT; internal energy of diatomic gas is 52RT\frac{5}{2}RT."

Syllabus Focus: Pressure of an Ideal Gas, Kinetic Interpretation of Temperature, and Law of Equipartition of Energy
✓ Core NEET UG Syllabus Anchor Syllabus & Academic Standards ↗

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