NEET 2021 Chemistry Question 65 Solution
Question
Which one of the following methods can be used to obtain highly pure metal which is liquid at room temperature?
- (1)Electrolysis
- (2)Chromatography
- (3)Distillation
- (4)Zone refining
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Which one of the following methods can be used to obtain highly pure metal which is liquid at room temperature?
The only metal that is liquid at room temperature is Mercury (). Mercury has an extraordinarily low boiling point (). The standard NCERT refining method for low-boiling metals (Zinc and Mercury) is DISTILLATION! Match Option (3)!
Mercury (, atomic number 80) is the only metallic element that exists in the liquid state at standard room temperature ( / ), having a melting point of .
NCERT categorizes metal refining processes based on physical properties: - Distillation: Used specifically for metals with low boiling points, such as Zinc () and Mercury (). The impure volatile metal is vaporized and condensed as pure distillate, leaving non-volatile impurities behind. - Electrolysis: Applied to reactive or common industrial metals like copper, aluminum, and gold. - Zone Refining: Applied to ultra-pure semiconductors (Germanium, Silicon, Boron, Gallium, Indium). - Chromatography: Utilized when elements to be separated are available in minute quantities and exhibit close chemical similarities.
Distillation is the designated metallurgical method to obtain highly pure mercury, corresponding to Option (3).
Diagnose every choice: Know exactly why the right option works and why distractors fail.
Standard refining method for copper, silver, and aluminum, but not the specific industrial method for liquid mercury.
Employed for microgram separations and lanthanoids/actinoids, not bulk mercury purification.
Verbatim NCERT refining method for low-boiling volatile metals like zinc and liquid mercury.
Used for solid semiconductor metals () based on fractional crystallization.
Students who see "highly pure metal" often instinctively guess Zone Refining (Option 4) because zone refining produces high-purity semiconductors. However, zone refining relies on a moving molten zone in a SOLID ingot, making it impossible for a metal that is already liquid at room temperature (Mercury).
"Distillation is used to refine low-boiling metals such as zinc and mercury by converting the metal into vapor while impurities remain behind."
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